Molecular and isotopic characterization of organic samples from the wreck of the Saint-Etienne merchant ship (XVIIIth century): Identification of pitch,fat, hair and sulfur     

Armelle Charrié-Duhaut  Jacques Connan  Mike Darnell  Jorge Spangenberg  Ewa Szymczyk  Adry Bissada  Pierre Albrecht 《Organic Geochemistry》2009,40(5):647-665

The wreck U Pezzo, excavated within the Saint Florent Gulf in northern Corsica was identified as the pink, Saint Etienne, a merchant ship which sank on January 31, 1769. In order to determine the composition of organic materials used to coat the hull or to waterproof different parts of the pink, a study of several samples, using molecular biomarker and carbon isotopic analysis, was initiated. The results revealed that the remarkable yellow coat, covering the outside planks of the ship’s bottom under the water line, is composed of sulfur, tallow (of ox and not of cetacean origin) and black pitch which corresponds to a mixture called “couroi” or “stuff”. Onboard ropes had been submitted to a tarring treatment with pitch. Hairs mixed with pitch were identified in samples collected between the two layers of the hull or under the sheathing planking. The study also provides a key model for weathering of pitch, as different degrees of degradation were found between the surface and the heart of several samples. Accordingly, molecular parameters for alteration were proposed. Furthermore novel mixed esters between terpenic and diterpenic alcohols and the free major fatty acids (C_14:0, C_16:0, C_18:0) were detected in the yellow coat.  相似文献   

Chemical and isotopic variations in the Wiśniówka Mała mine pit water,Holy Cross Mountains (south-central Poland)     

Zdzisław M. Migaszewski  Agnieszka Gałuszka  Stanisław Hałas  Józef Dąbek  Sabina Dołęgowska  Irena Budzyk  Ewa Starnawska  Artur Michalik 《Environmental Geology》2009,57(1):29-40

In 2005 and 2006, hydrogeochemical study was carried out in the bipartite Wiśniówka Mała pit lake of the Holy Cross Mountains (south-central Poland). This is the largest acidic water body in Poland. This report presents the element concentrations in the water and sediment, stable sulfur and oxygen isotope ratios in the soluble sulfates, and stable oxygen isotope ratio in the water. The scope of the investigation also encompassed mineralogical examinations (scanning electron microscope, X-ray diffraction) of the sediment. The results of this study show that there is a spatial and temporal variability in concentrations of most elements and sulfur isotope ratios in the examined pit lake. The water of the western pond displayed a lower pH with a mean of 3.73 and higher conductivity (390 μS cm⁻¹) as well as higher concentrations of sulfates (156 mg L⁻¹) and most of the cations and anions. The concentrations of Fe²⁺ and Fe³⁺ averaged 0.8 and 0.4 mg·L⁻¹. In contrast, the eastern pond water revealed a higher pH (mean of 4.36), lower conductivity (293 μS cm⁻¹) and lower sulfate (90 mg L⁻¹) and trace metal levels. Similar variations were recorded in the stable sulfur isotope ratios. The δ³⁴S_V-CDT(SO₄ ²⁻) values in the water of the western pit pond were in the range of −6.7 to −4.6‰ (mean of −5.6‰), whereas that in the eastern pit pond ranged from −2.2 to −0.9‰ (−1.6‰). The alkalinity of the entire lake water was below 0.1 mg·L⁻¹ CaCO₃. No distinct difference in the δ¹⁸O_V-SMOW(SO₄ ²⁻) was noted between the western and eastern pit ponds. Compared to the Purple Pond in the Sudetes (Poland) and similar sites throughout the world, the examined pit lake is highlighted by distinctly low concentrations of sulfates, iron and other trace metals. Based on this and other studies performed in the Holy Cross Mountains, a conclusion can be drawn that the SO₄ ²⁻ in the Wiśniówka Mała pit lake water is a mixture of SO₄ ²⁻ derived from the following sources: (1) pyrite oxidation (especially in the western pond water), (2) leaching of soluble sulfates from soils and waste material, as well as (3) subordinate deposition of airborne sulfate precipitation.  相似文献   

Applying numerical modeling for designing strategies of effective groundwater remediation     

Aleksandra Kiecak  Grzegorz Malina  Ewa Kret  Tadeusz Szklarczyk 《Environmental Earth Sciences》2017,76(6):248

Selection of effective groundwater remediation scenarios is a complex issue that requires understanding of contaminants’ transport processes. The effectiveness of cleanup measures may be verified by fate and transport numerical modeling. The goal of this work was to present the usefulness of fate and transport modeling for planning, verification and fulfillment of effective groundwater remediation methods. Selection methodology was developed, which is based on results of numerical flow and transport modeling. A field site located in south-east Poland was selected as a case study, in which groundwater contamination of trichloroethene and tetrachloroethene was detected. The results indicated that “pump and treat” was the most effective among the studied remediation methods, followed by permeable reactive barrier and in situ chemical oxidation. Natural attenuation-based remediation was demonstrated to be the least suitable, as it requires the longest time to reach predefined remediation goals, principally due to low sorption capacity and unfavorable hydrogeochemical conditions for biodegradation. Fate and transport numerical modeling allowed simulating different remediation strategies, and thus the decision-making process was facilitated.  相似文献   

Multi-sensor DInSAR applied to the spatiotemporal evolution analysis of ground surface deformation in Cerro Prieto basin,Baja California,Mexico, for the 1993–2014 period     

Olga Sarychikhina  Ewa Glowacka  Braulio Robles 《Natural Hazards》2018,92(1):225-255

The combined effects of active tectonics and anthropogenic activities, primarily geothermal resources exploitation for electricity production in Cerro Prieto geothermal field, influence the ground surface deformation in Cerro Prieto basin, Baja California, Mexico. In this study, a large set of multi-sensor C-band SAR images have been employed to reconstruct the spatiotemporal evolution of aseismic ground surface deformation that has affected Cerro Prieto basin from 1993 to 2014. Conventional DInSAR together with the interferograms stacking procedure was applied. The results showed that the study area presented considerable surface deformation (mainly subsidence) during the entire time of the investigation. The main changes in rate and pattern of surface deformation have a good correlation in time and space with the changes in production in the Cerro Prieto geothermal field. Comparison of LOS displacement maps from different viewing geometries, and decomposition (where possible) of LOS displacement into vertical and horizontal (east–west) components, revealed considerable horizontal displacement which mostly reflects the ground movement at and beyond the margin of the subsidence basin toward the areas of highest subsidence rates. In addition, the validation of the DInSAR results by comparing them against measurements from leveling surveys was performed, confirming the high reliably of satellite interferometry for the ground surface deformation rate mapping in the study area.  相似文献   

Determination of volatile concentrations in fluorapatite of Martian shergottite NWA 2975 by combining synchrotron FTIR,Raman spectroscopy,EMPA, and TEM,and inferences on the volatile budget of the apatite host‐magma          下载免费PDF全文

Ewa Słaby  Monika Koch‐Müller  Hans‐Jürgen Förster  Richard Wirth  Dieter Rhede  Anja Schreiber  Ulrich Schade 《Meteoritics & planetary science》2016,51(2):390-406

We combined the focused ion beam sample preparation technique with polarized synchrotron‐based FTIR (Fourier transform infrared) spectroscopy, laser‐Raman spectroscopy, electron microprobe analysis (EMPA), and transmission electron microscope (TEM) analysis to identify and quantify structurally bound OH, F, Cl, and CO₃ groups in fluorapatite from the Northwest Africa 2975 (NWA 2975) shergottite. In this study, the first FTIR spectra of the OH‐stretching region from a Martian apatite are presented that show characteristic OH‐bands of a F‐rich, hydroxyl‐bearing apatite. Depending on the method of apatite‐formula calculation and whether charge balance is assumed or not, the FTIR‐based quantification of the incorporated OH, expressed as wt% H₂O, is in variably good agreement with the H₂O concentration calculated from electron microprobe data. EMP analyses yielded between 0.35 and 0.54 wt% H₂O, and IR data yielded an average H₂O content of 0.31 ± 0.03 wt%, consistent with the lower range determined from EMP analyses. The TEM observations implied that the volatiles budget of fluorapatite is magmatic. The water content and the relative volatile ratios calculated for the NWA 2975 magma are similar to those established for other enriched or intermediate shergottites. It is difficult to define the source of enrichment: either Martian wet mantle or crustal assimilation. Comparing the environment of parental magma generation for NWA 2975 with the terrestrial mantle in terms of water content, it displays a composition intermediate between enriched and depleted MORB.  相似文献   

The circulation, water masses and sea-ice of Baffin Bay   总被引：2，自引：0，他引：2  

Charles C.L Tang  Charles K. Ross  Tom Yao  Brian Petrie  Brendan M. DeTracey  Ewa Dunlap 《Progress in Oceanography》2004,63(4):183-228

The oceanographic, meteorological and sea-ice conditions in Baffin Bay are studied using historical hydrographic, satellite and meteorological data, and a set of current meter data from a mooring program of the Bedford Institute of Oceanography. Baffin Bay is partially covered by sea-ice all year except August and September. The interannual variation of the ice extent is shown to be correlated with winter air temperature. Available hydrographic data were used to study the water masses and the horizontal and vertical distribution of temperature/salinity. Three water masses can be identified – Arctic Water in the upper 100–300 m of all regions except the southeast, West Greenland Intermediate Water at 300–800 m in most of the interior of Baffin Bay, and Deep Baffin Bay Water in all regions below 1200 m. The temperature and salinity in Baffin Bay have limited seasonal variability except in the upper 300 m of eastern Davis Strait, northern Baffin Bay and the mouth of Lancaster Sound. Summer data have a temperature minimum at 100 m, which suggests winter convection does not penetrate deeper than this depth. Current meter data and results of a circulation model indicate that the mean circulation is cyclonic. The seasonal variation of the currents is complex. Overall, summer and fall tend to have stronger currents than winter and spring at all depths. Among the different regions, the largest seasonal variation occurs at the mouth of Lancaster Sound and the Baffin Island slope. Model generated velocity fields show a basic agreement with the observed currents, and indicate strong topographic control in the vicinity of Davis Strait and on the Greenland shelves. The model also produces a southward counter current on the Greenland slope, which may explain the observed high horizontal shears over the Greenland slope. Estimates of the volume and fresh water transports through Lancaster, Jones and Smith Sounds are reviewed. Transports through Davis Strait are computed from the current meter data. The balance of freshwater budget and sensitivity of the thermohaline circulation to freshwater transport are discussed.  相似文献   

Geochemistry and stable sulfur and oxygen isotope ratios of the Podwiśniówka pit pond water generated by acid mine drainage (Holy Cross Mountains, south-central Poland)     

Zdzis&#x;aw M. Migaszewski  Agnieszka Ga&#x;uszka  Stanis&#x;aw Ha&#x;as  Sabina Do&#x;&#x;gowska  Jzef D&#x;bek  Ewa Starnawska 《Applied Geochemistry》2008,23(12):3620-3634

  相似文献   

Pesticides from the EU First and Second Watch Lists in the Water Environment     

Damian Pietrzak  Jaros&#x;aw Kania  Grzegorz Malina  Ewa Kmiecik  Katarzyna W&#x;tor 《洁净——土壤、空气、水》2019,47(7)

  相似文献   

The mass and anisotropy profiles of galaxy clusters from the projected phase-space density: testing the method on simulated data     

Rados&#;aw Wojtak  Ewa L. &#;okas  Gary A. Mamon  Stefan Gottlöber 《Monthly notices of the Royal Astronomical Society》2009,399(2):812-821

We present a new method of constraining the mass and velocity anisotropy profiles of galaxy clusters from kinematic data. The method is based on a model of the phase-space density, which allows the anisotropy to vary with radius between two asymptotic values. The characteristic scale of transition between these asymptotes is fixed and tuned to a typical anisotropy profile resulting from cosmological simulations. The model is parametrized by two values of anisotropy, at the centre of the cluster and at infinity, and two parameters of the NFW density profile, the scale radius and the scale mass. In order to test the performance of the method in reconstructing the true cluster parameters, we analyse mock kinematic data for 20 relaxed galaxy clusters generated from a cosmological simulation of the standard Λ cold dark matter model. We use Bayesian methods of inference and the analysis is carried out following the Markov Chain Monte Carlo approach. The parameters of the mass profile are reproduced quite well, but we note that the mass is typically underestimated by 15 per cent, probably due to the presence of small velocity substructures. The constraints on the anisotropy profile for a single cluster are in general barely conclusive. Although the central asymptotic value is determined accurately, the outer one is subject to significant systematic errors caused by substructures at large clustercentric distance. The anisotropy profile is much better constrained if one performs joint analysis of at least a few clusters. In this case, it is possible to reproduce the radial variation of the anisotropy over two decades in radius inside the virial sphere.  相似文献   

Long-term variability of occurrence of precipitation forms in winter in Kraków, Poland   总被引：1，自引：0，他引：1  

Robert Twardosz  Ewa ?upikasza  Tadeusz Nied?wied?  Adam Walanus 《Climatic change》2012,113(3-4):623-638

The paper discusses long-term change in snowfall, rainfall and mixed precipitation viewed in conjunction with air temperature and North Atlantic Oscillation (NAO) in winter (December–February). In the study of contemporary climate change and its effect on the hydrological cycle it is useful to focus on winter precipitation forms. A 146-year secular observation series from Kraków, spanning the period 1863–2008, was used to extract data on the number of days with precipitation and on precipitation amount broken down by form. Statistically significant trends were found in total and mixed precipitation, but not in snowfall and rainfall. The climate warming effect has contributed to a material decrease in the snowfall to total winter precipitation ratio during the second half of the 20th c. The highest impact of air temperature was found in the wintertime variation in number of days with snowfall while the NAO had a significant influence on the frequency and amount of both rainfall and snowfall.  相似文献